You could use a ControlTemplate to achieve that:
<Style x:Key="ButtonStyle" TargetType="{x:Type Button}">
<Setter Property="Background" Value="Black"/>
<Setter Property="Template">
<Setter.Value>
<ControlTemplate TargetType="{x:Type Button}">
<Path Fill="{TemplateBinding Background}"
Data="M 0,0 A 100,100 90 0 0 100,100 L 100,100 100,0" />
</ControlTemplate>
</Setter.Value>
</Setter>
</Style>
Than you apply it to the button:
<Button Style="{StaticResource ButtonStyle}"/>
If you need some references to draw the "Path" check this MSDN link.
Update
To show the content you should use a ContentPresenter, something like this:
<Style x:Key="ButtonStyle" TargetType="{x:Type Button}">
<Setter Property="Background" Value="Black"/>
<Setter Property="HorizontalAlignment" Value="Center"/>
<Setter Property="VerticalContentAlignment" Value="Center"/>
<Setter Property="Template">
<Setter.Value>
<ControlTemplate TargetType="{x:Type Button}">
<Grid>
<Path Fill="{TemplateBinding Background}"
Data="M 0,0 A 100,100 90 0 0 100,100 L 100,100 100,0" />
<ContentPresenter VerticalAlignment="{TemplateBinding VerticalContentAlignment}"
HorizontalAlignment="{TemplateBinding HorizontalAlignment}"/>
</Grid>
</ControlTemplate>
</Setter.Value>
</Setter>
</Style>
In the button:
<Button Style="{StaticResource ButtonStyle}" Foreground="White">
test
</Button>
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