RFC822 ("Standard for the Format of ARPA Internet Text Messages") specified in sections 4.7.4 and 4.7.5 that headers beginning with "X-" would not ever be part of any standard, and thus can be used for application-specific purposes.
For what it's worth, the more recent BCP document RFC6648 ("Deprecating the 'X-' Prefix and Similar Constructs in Application Protocols") recommends that the use of the "X-" prefix be avoided in the future, as the distinction between standardized and nonstandardized headers is not well defined, and attempting to draw such a distinction fails when commonly used nonstandard headers are adopted as standards.
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