You can achieve that by specifying the scope of you fields like this:
=First(Fields!fieldName_A.Value, "Dataset1") / First(Fields!fieldName_B.Value, "Dataset2")
Assuming A is 10 and B is 2 and they are of type numeric then you will have the result of 5 when the report renders.
When you are in the expression builder you can choose the Category: Datasets, your desired dataset highlighted under Item: and then double click the desired field under Value: and it will appear in your expression string with the scope added.
Using same logic you can concatenate two fields like so:
=First(Fields!fieldName_A.Value, "Dataset1") & “ “ & First(Fields!fieldName_B.Value, "Dataset2")
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