The message is from the C# web service side ("Object reference not set to an instance of an object" is basically a Java equivalent of NullPointerException) but it might be because of something you send from your Java client or maybe you don't send.
The error usually means that you didn't send a required parameter and that the web service didn't do a proper job of validating it's input and missing parameter got to a point when caused the NullReferenceException.
But there is only one way to be sure, and that is to troubleshoot the call.
I suggest you use something like SoapUI to create a message and send that to the service. Once you get a succesfull call in SoapUI, make a call with the same parameters from your Java client and see what happens. When you do that, using a proxy for logging is very useful to see if the sent message is actually the expected one.
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