The keys used are the ordinals of the characters, not the characters themselves:
'a'.translate({ord('a'): 'b'})
It's easier to use str.maketrans
>>> 'a'.translate(str.maketrans('a', 'b'))
'b'
>>> help(str.translate)
Help on method_descriptor:
translate(...)
S.translate(table) -> str
Return a copy of the string S, where all characters have been mapped
through the given translation table, which must be a mapping of
Unicode ordinals to Unicode ordinals, strings, or None.
Unmapped characters are left untouched. Characters mapped to None
are deleted.
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