WCF only serializes structure, because what ends up on the wire must be self-contained enough to be useful for any client, not just .NET clients.
Some client developed on a different platform may not share the concept of a 'dictionary', so it would be too constraining to serialize a Dictionary to a representation that carries an implicit knowledge about the underlying class.
The client may not even be object-oriented.
A Dictionary is more than structure - it also contains behavior (e.g. when you assign to a key that already exists, you overwrite that key, etc.) and that behavior cannot travel across the wire.
In other words, Dictionaries and many other .NET types are not interoperable, so WCF will not attempt to preserve them in a ServiceContract
.
You would probably be better off designing a custom DataContract
for your data.
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