The reason behind above behavior is data structure alignment and padding. Basically if you are creating a 4 byte variable e.g. int, it will be aligned to a four byte boundary i.e. it will start from an address in memory, which is multiple of 4. Same applies to other data types. 2 byte short should start from even memory address and so on.
Hence if you have a 1 byte character declared before the int (assume 4 byte here), there will be 3 free bytes left in between. The common term used for them is 'padded'.
Data structure alignment
Another good pictorial explanation
Reason for alignment
Padding allows faster memory access i.e. for cpu, accessing memory areas that are aligned is faster e.g. reading a 4 byte aligned integer might take a single read call where as if an integer is located at a non aligned address range (say address 0x0002 - 0x0006), then it would take two memory reads to get this integer.
One way to force compiler to avoid alignment is (specific to gcc/g++) to use keyword 'packed' with the structure attribute. packed keyword Also the link specifies how to enforce alignment by a specific boundary of your choice (2, 4, 8 etc.) using the aligned keyword.
Best practice
It is always a good idea to structure your class/struct in a way that variables are already aligned with minimum padding. This reduces the size of the class overall plus it reduces the amount of work done by the compiler i.e. no rearrangement of structure. Also one should always access member variables by their names in the code, rather than trying to read a specific byte from structure assuming a value would be located at that byte.
Another useful SO question on performance advantage of alignment
For the sake of completion, following would still have a size of 8 bytes in your scenario (32 bit machine), but it won't get any better since full 8 bytes are now occupied, and there is no padding.
class temp
{
public:
int i;
short s;
char c;
char c2;
};
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