You can add do that without problem only if your table doesn't have relationship with others.
You must remove the old primary key and upload the table accordingly (perhaps add an unique index on the old primary key).
Proceed like that :
ALTER TABLE XXX DROP PRIMARY KEY
- Add the new column like that
ALTER TABLE XXX add column Id INT NOT NULL AUTO_INCREMENT FIRST, ADD primary KEY Id(Id)
The table will be looked and the AutoInc updated.
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