0x000001 is the NAL start prefix code (it can also be 0x00000001, depends on the encoder implementation). 0x09 is 0b00001001, which means F=0, NRI = 0, and type is 0b01001. That particular type is an access unit delimiter. Notice that it is immediately followed by another NAL unit defined by 0x67, which is a NAL type of 7, which is the sequence parameter set.
There's also the picture parameter set:
00 0001 68...
...and the start of a keyframe:
0000 0001 65...
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…