Method 1: Bat file.
If you have python in the PATH Environment variable:
start python D:pys1.py
start python D:pys2.py
Else literal path
start C:python27python.exe D:pys1.py
start C:python27python.exe D:pys2.py
Note that this will not wait for a return from either execution. Note, do not forget to add quotations around the path strings if they contain spaces or special characters.
See start /?
for more help and options.
Method 2: Two different Scheduled Tasks
Create two separate scheduled tasks that start at the same time each calling python to run one of the scripts.
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