The only significant difference I know is in the treatment of explicit
constructors:
struct foo
{
explicit foo(int);
};
foo f0 {42}; // OK
foo f1 = {42}; // not allowed
This is similar to the "traditional" initialization:
foo f0 (42); // OK
foo f1 = 42; // not allowed
See [over.match.list]/1.
Apart from that, there's a defect (see CWG 1270) in C++11 that allows brace-elision only for the form T a = {something}
struct aggr
{
int arr[5];
};
aggr a0 = {1,2,3,4,5}; // OK
aggr a1 {1,2,3,4,5}; // not allowed
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