You may use
a.reduce Hash.new, :merge
which directly yields
{:a=>:b, :c=>:d}
Note that in case of collisions the order is important. Latter hashes override previous mappings, see e.g.:
[{a: :b}, {c: :d}, {e: :f, a: :g}].reduce Hash.new, :merge # {:a=>:g, :c=>:d, :e=>:f}
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…