Such rewriting can be done by forming a Groebner basis of the replacement polynomials, with respect to a variable order that favors using a-f over w-z. Then use PolynomialReduce
with respect to the same order to rewrite your polynomial.
Here is an example. I'll start with replacement rules so I can construct a polynomial such that we know the expected result.
reprules = {a -> w*z, b -> x*y, c -> (w^3 + z^3),
d -> (x + y), e -> (w^3*x + y*z^3), f -> (w^3*y + x*z^3)};
Now recast as polynomial relations.
reppolys = Apply[Subtract, reprules, 1];
Here we create an example.
poly =
a^2*b + 3*b^2*c^3 - 2*d*e*f + 11*b*f^2 - 5 a*d^2*e /. reprules // Expand
Out[11]= -2*w^6*x^2*y - 2*w^6*x*y^2 + 3*w^9*x^2*y^2 + 11*w^6*x*y^3 -
5*w^4*x^3*z - 10*w^4*x^2*y*z - 5*w^4*x*y^2*z + w^2*x*y*z^2 - 2*w^3*x^3*z^3 -
2*w^3*x^2*y*z^3 - 2*w^3*x*y^2*z^3 + 22*w^3*x^2*y^2*z^3 + 9*w^6*x^2*y^2*z^3 -
2*w^3*y^3*z^3 - 5*w*x^2*y*z^4 - 10*w*x*y^2*z^4 - 5*w*y^3*z^4 -
2*x^2*y*z^6 + 11*x^3*y*z^6 - 2*x*y^2*z^6 + 9*w^3*x^2*y^2*z^6 + 3*x^2*y^2*z^9
Form the Groebner basis mentioned above.
gb = GroebnerBasis[reppolys, {w, x, y, z, a, b, c, d, e, f}];
Use it to reduce our input to recover the expected result.
PolynomialReduce[poly,
gb, {w, x, y, z, a, b, c, d, e, f}][[2]]
Out[12]= a^2*b + 3*b^2*c^3 - 5*a*d^2*e - 2*d*e*f + 11*b*f^2
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A comment asks about descriptions of Groebner bases. For my own take on the Mathematica functionality, there is an elderly TMJ article. Can be found at
http://library.wolfram.com/infocenter/Articles/2179/
Among the better books related to this topic there is the UTM series text
Ideals, Varieties, and Algorithms by Cox, Lottle, and O'Shea.
An Introduction to Gr?bner Bases by Adams and Loustaunau (AMS) is also quite good.
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Daniel Lichtblau