using System.Security.Cryptography;
        /// <param name="pToEncrypt">要加密的字符串。</param>
        /// <param name="sKey">密钥，且必须为8位。</param>
        /// <returns>以Base64格式返回的加密字符串。</returns>
        public string Encrypt(string pToEncrypt, string sKey)
        {
            using (DESCryptoServiceProvider des = new DESCryptoServiceProvider())
            {
                byte[] inputByteArray = Encoding.UTF8.GetBytes(pToEncrypt);
                des.Key = ASCIIEncoding.ASCII.GetBytes(sKey);
                des.IV = ASCIIEncoding.ASCII.GetBytes(sKey);
                System.IO.MemoryStream ms = new System.IO.MemoryStream();
                using (CryptoStream cs = new CryptoStream(ms, des.CreateEncryptor(), CryptoStreamMode.Write))
                {
                    cs.Write(inputByteArray, 0, inputByteArray.Length);
                    cs.FlushFinalBlock();
                    cs.Close();
                }
                string str = Convert.ToBase64String(ms.ToArray());
                ms.Close();
                return str;
            }
        }

        /// <param name="pToDecrypt">要解密的以Base64</param>
        /// <param name="sKey">密钥，且必须为8位。</param>
        /// <returns>已解密的字符串。</returns>
        public string Decrypt(string pToDecrypt, string sKey)
        {
            byte[] inputByteArray = Convert.FromBase64String(pToDecrypt);
            using (DESCryptoServiceProvider des = new DESCryptoServiceProvider())
            {
                des.Key = ASCIIEncoding.ASCII.GetBytes(sKey);
                des.IV = ASCIIEncoding.ASCII.GetBytes(sKey);
                System.IO.MemoryStream ms = new System.IO.MemoryStream();
                using (CryptoStream cs = new CryptoStream(ms, des.CreateDecryptor(), CryptoStreamMode.Write))
                {
                    cs.Write(inputByteArray, 0, inputByteArray.Length);
                    cs.FlushFinalBlock();
                    cs.Close();
                }
                string str = Encoding.UTF8.GetString(ms.ToArray());
                ms.Close();
                return str;
            }
        }       

PHP代码：

<?php
class DES {
    var $key;
    var $iv; //偏移量

   
    function DES($key, $iv = 0) {
        //key长度8例如:1234abcd
        $this->key = $key;
        if ($iv == 0) {
            $this->iv = $key; //默认以$key 作为 iv
        } else {
            $this->iv = $iv; //mcrypt_create_iv ( mcrypt_get_block_size (MCRYPT_DES, MCRYPT_MODE_CBC), MCRYPT_DEV_RANDOM );
        }
    }

    function encrypt($str) {
        //加密，返回值使用base64重编码
        $size = mcrypt_get_block_size(MCRYPT_DES, MCRYPT_MODE_CBC);
        $str = $this->pkcs5Pad($str, $size);
        return base64_encode(mcrypt_cbc(MCRYPT_DES, $this->key, $str, MCRYPT_ENCRYPT, $this->iv));
    }

    function decrypt($str) {
        //解密 输入值是base64重编码过的
        $strBin = base64_decode($str);
        $str = mcrypt_cbc(MCRYPT_DES, $this->key, $strBin, MCRYPT_DECRYPT, $this->iv);
        $str = $this->pkcs5Unpad($str);
        return $str;
    }

   
    function pkcs5Unpad($text) {
        $pad = ord($text{strlen($text) - 1});
        if ($pad > strlen($text)) return false;
        if (strspn($text, chr($pad), strlen($text) - $pad) != $pad) return false;
        return substr($text, 0, -1 * $pad);
    }

   
    function pkcs5Pad($text, $blocksize) {
        $pad = $blocksize - (strlen($text) % $blocksize);
        return $text . str_repeat(chr($pad), $pad);
    }

}
?>