SOLUTION
The way to resolve this issue is by editing your System Environment Variables. In my case my System Path Variable had a string which was over 2048 characters, which apparently causes random path haywire at unpredictable times. By making sure this is below 2048 characters, it will solve the problem. Make sure you restart explorer.exe after changing the path variables and getting them under 2048 characters.
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…