There is no exposed means of setting the content-type on the messages sent from the Qpid JMS client. The client itself uses this field as part of the JMS mapping to AMQP to distinguish certain message types that it sends and to determine at receive time what certain messages should be presented as.
It is technically possible to use reflection to reach in and so the value but the APIs you have to use from the JmsMessageFacade class are not public and could change with any release so choosing to do so comes with significant risk.
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