You should generate rows first, before join them with your table like below. I use the with clause here to generate the 18 rows in your sample.
with rws (grade, ext) as (
select ceil(level/3), decode(mod(level, 3), 0, '+', 1, '-', null)
from dual
connect by level <= 3 * 6
)
select r.grade, r.ext, nvl2(t.Ext, 1, 0) studentGrade
from rws r
left join your_table t
on t.Grade = r.Grade and decode(t.Ext, r.Ext, 1, 0) = 1
order by 1 desc, decode(r.ext, null, 2, '-', 3, '+', 1)
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