Try with concat
df = pd.DataFrame()
s = pd.Series({ 1: 'one', 2: 'two', 3: 'three'})
df['aaa'] = s
s = pd.Series({ 1: 'one', 5: 'two', 6: 'three'}, name='bbb')
df = pd.concat([df,s], axis=1)
df
Out[150]:
aaa bbb
1 one one
2 two NaN
3 three NaN
5 NaN two
6 NaN three
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