Is it possible to add dedicated SQL server VM to azure synapse sql pool for machine learning purposes?
No. You can only create a new dedicated sql pool.
Moreover, the official guide is to use AML service for ML related experiments - both training and inference. Here is a guide: https://docs.microsoft.com/en-us/azure/synapse-analytics/machine-learning/tutorial-sql-pool-model-scoring-wizard
If you wanna use your dedicated SQL Server VM, it can be used as Integration->Integration runtimes->Self-hosted. But that is for data flows/pipelines so totally different objective (ref: Azure Data Factory).
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