Java
Yes, it is possible. The following example is in Java:
WebDriver driver = new FirefoxDriver();
driver.get("http://www.google.com/");
File scrFile = ((TakesScreenshot)driver).getScreenshotAs(OutputType.FILE);
// Now you can do whatever you need to do with it, for example copy somewhere
FileUtils.copyFile(scrFile, new File("c:\tmp\screenshot.png"));
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