The terms do appear to be defined differently, but I've always thought of one implying the other; I can't think of any case when an expression is referentially transparent but not pure, or vice-versa.
Wikipedia maintains separate articles for these concepts and says:
From Referential transparency:
If all functions involved in the
expression are pure functions, then
the expression is referentially
transparent. Also, some impure
functions can be included in the
expression if their values are
discarded and their side effects are
insignificant.
From Pure expressions:
Pure functions are required to
construct pure expressions. [...] Pure
expressions are often referred to as
being referentially transparent.
I find these statements confusing. If the side effects from a so-called "impure function" are insignificant enough to allow not performing them (i.e. replace a call to such a function with its value) without materially changing the program, it's the same as if it were pure in the first place, isn't it?
Is there a simpler way to understand the differences between a pure expression and a referentially transparent one, if any? If there is a difference, an example expression that clearly demonstrates it would be appreciated.
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